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In Fig. 3.7 the left- and right-hand barriers are varied in thickness to illustrate the effect on the solution for the energy produced by this numerical method, for the single quantum well of above. Clearly, the energy converges to a constant, which is the true stationary state in this case, the ground state E1 . Thus if the energy is the only motivation for the calculation, any barrier width beyond, say 150 A, will suffice. Although note this can vary depending on the barrier height, well width and carrier effective mass. If the wave function is also desired, e.g. to be used as an input for calculating another property, such as the exciton binding energy or an electron-phonon scattering rate, then greater care has to be taken. While very large outer barrier layers can be chosen to ensure convergence of the eigenenergy, this can have a detrimental effect on the wave function, as can be seen in Fig. 3.8. At too narrow a barrier width,

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e.g. the 60 A case, although the energy may be returned to within 1 meV, the wave function doesn't satisfy the second of the standard boundary conditions, i.e. u' = 0. With a 200 A barrier, which corresponds to just after the energy has converged, the wave function is as expected and satisfies both the standard boundary conditions this represents the optimal barrier width. However at very large barrier widths, such as 600 A as illustrated, the wave function is beginning to diverge and as stated above, although the energy obtained from such a solution is reliable, the wave function cannot be used to calculate other properties. The energy E can always be obtained to far higher accuracy than would be required for comparison of say, electron confinement energies with photoluminescence data. Computer codes typically assign 16-figure accuracy to a double precision number, and the shooting method can be used to determine E to 12 of these, for example. However, even at this high accuracy the wave function at the end of an iteration, i.e., the value of u(oo, E} = u(v, E}, cannot be made equal to zero for large barrier widths, simply because E cannot be stored to enough significant figures. If 32-figure accuracy could be used in the computing, then the wave function could be returned realistically for larger barrier widths. The wave functions obtained from this numerical method are not normalised, i.e. they do not satisfy:

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